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Minsung Park1, Sungmin Seo, In Su Lee

  • 1Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, Korea.

Chemical Communications (Cambridge, England)
|April 23, 2010
PubMed

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Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...