Related Experiment Video
Updated: Jun 13, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
Both [2+2] and [2+4] additions of inert aromatics via identical ternary host-guest complexes
Shinnosuke Horiuchi1, Yuki Nishioka, Takashi Murase
1Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Abstract:
A self-assembled coordination cage enables inert aromatics to undergo both [2+2] and [2+4] cycloadditions by encapsulating them within the cavity. Aceanthrylene reacts with a maleimide derivative under thermal and photo-irradiation conditions to give a product as a single regio- and stereoisomer.
More Related Videos
07:50Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
Published on: May 26, 2019
10:17Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
Published on: February 7, 2019
Related Concept Videos
Cycloaddition Reactions: MO Requirements for Thermal Activation
Cycloaddition Reactions: Overview
Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene
[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction
Conjugate Addition to α,β-Unsaturated Carbonyl Compounds
Nucleophilic Aromatic Substitution: Elimination–Addition