Spatial variability of intake fractions for Canadian emission scenarios: a comparison between three resolution scales

Spatially differentiated intake fractions (iFs) linked to Canadian emissions of toxic organic chemicals were developed using the multimedia and multipathways fate and exposure model IMPACT 2002. The fate and exposure of chemicals released to the Canadian environment were modeled with a single regional mass-balance model and three models that provided multiple mass-balance regions within Canada. These three models were based on the Canadian subwatersheds (172 zones), ecozones (15 zones), and provinces (13 zones). Releases of 32 organic chemicals into water and air were considered. This was done in order to (i) assess and compare the spatial variability of iFs within and across the three levels of regionalization and (ii) compare the spatial iFs to nonspatial ones. Results showed that iFs calculated using the subwatershed resolution presented a higher spatial variability (up to 10 orders of magnitude for emissions into water) than the ones based on the ecozones and provinces, implying that higher spatial resolution could potentially reduce uncertainty in iFs and, therefore, increase the discriminating power when assessing and comparing toxic releases for known emission locations. Results also indicated that, for an unknown emission location, a model with high spatial resolution such as the subwatershed model could significantly improve the accuracy of a generic iF. Population weighted iFs span up to 3 orders of magnitude compared to nonspatial iFs calculated by the one-box model. Less significant differences were observed when comparing spatial versus nonspatial iFs from the ecozones and provinces, respectively.