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Printing Fabrication of Bulk Heterojunction Solar Cells and In Situ Morphology Characterization
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A facile route to polymer solar cells with optimum morphology readily applicable to a roll-to-roll process without

Hui Joon Park1, Myung-Gyu Kang, Se Hyun Ahn

  • 1Macromolecular Science and Engineering, The University of Michigan, Ann Arbor, MI 48109, USA.

Advanced Materials (Deerfield Beach, Fla.)
|April 28, 2010
PubMed
Abstract

No abstract available in PubMed .

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...

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