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Updated: Jun 13, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
A facile photosynthesis of trans-dioxoruthenium(VI) porphyrins
Yan Huang1, Eric Vanover, Rui Zhang
1Department of Chemistry, Western Kentucky University, 1906 College Heights Blvd., Bowling Green, Kentucky, USA.
Abstract:
Photolysis of porphyrin-ruthenium(IV) dichlorate complexes with visible light results in homolytic cleavage of the O-Cl bond in the chlorates to form trans-dioxoruthenium(VI) species bearing either sterically encumbered or unencumbered porphyrin ligands.
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