Related Experiment Video
Updated: Jun 13, 2026
Quantification of Metal Leaching in Immobilized Metal Affinity Chromatography
Published on: January 17, 2020
Simultaneous determination of copper, lead, and cadmium at hexagonal mesoporous silica immobilized quercetin modified
Fangquan Xia1, Xin Zhang, Changli Zhou
1School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022 Shandong, China. chm_xiafq@ujn.edu.cn
Abstract:
A new method was developed for simultaneous determination of copper, lead, and cadmium, based on their voltammetric response at a carbon paste electrode modified with hexagonal mesoporous silica (HMS) immobilized quercetin (HMS-Qu/CPE). Compared with quercetin modified carbon paste electrode (Qu/CPE) and quercetin ionic liquid modified carbon paste electrode (Qu-IL/CPE), the HMS-Qu/CPE exhibited improved selectivity and high sensitivity toward the detection of copper, lead, and cadmium. The properties of the HMS-Qu/CPE in 0.1 M HCOONa-HCl buffer solution (pH 4.7) were investigated by adsorptive stripping voltammetry (ASV) and electrochemical impedance spectroscopy (EIS). The electrochemical behavior of copper, lead, and cadmium at the modified electrodes and factors affecting the preconcentration procedures were also investigated. Detection limits of 5.0, 0.8, 1.0 nM for copper, lead, and cadmium were obtained, respectively. The method is simple, fast, sensitive, and selective, and is successfully applied to soil sample.
More Related Videos
09:51TD-DFT Guided Advanced E-Eye Sensing Technique for On-site Quantification of Fe, Cr, F, and As in the Environmental, Biological, and Food Samples
Published on: September 19, 2025
10:31Detection and Recovery of Palladium, Gold and Cobalt Metals from the Urban Mine Using Novel Sensors/Adsorbents Designated with Nanoscale Wagon-wheel-shaped Pores
Published on: December 6, 2015
