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Updated: Jun 13, 2026

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction
12:22

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

Published on: February 4, 2013

Synthesis of samarium(II) borohydrides and their behaviour as initiators in styrene and epsilon-caprolactone

Florian Jaroschik1, Fanny Bonnet, Xavier-Frédéric Le Goff

  • 1Laboratoire Hétéroéléments et Coordination, CNRS, Ecole Polytechnique, Route de Saclay, 91128, Palaiseau, France.

Dalton Transactions (Cambridge, England : 2003)
|May 8, 2010
PubMed

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