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Updated: Jun 13, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Activation of H2 by a highly distorted Rh(II) complex with a new C3-symmetric tripodal tetraphosphine ligand
Jeroen Wassenaar1, Bas de Bruin, Maxime A Siegler
1Supramolecular & Homogeneous Catalysis Group, van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Abstract:
Facile oxidation of a sterically encumbered Rh(I) complex generates a stable Rh(II) metalloradical species; the latter is able to activate H(2) under formation of the corresponding Rh(III) complex.
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