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Stabilization of Pd(III) states in nano-wire coordination complexes

Masahiro Yamashita1, Shinya Takaishi

  • 1Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan. yamasita@agnus.chem.tohoku.ac.jp

Chemical Communications (Cambridge, England)
|May 21, 2010
PubMed
Summary

Researchers achieved the Mott-Hubbard (MH) state in palladium (Pd) complexes, previously only seen in nickel (Ni) complexes. This breakthrough was enabled by controlling palladium-palladium distances, offering new insights into halogen-bridged metal complexes.

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