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Updated: Jun 12, 2026

Fabrication of Schottky Diodes on Zn-polar BeMgZnO/ZnO Heterostructure Grown by Plasma-assisted Molecular Beam Epitaxy
Published on: October 23, 2018
Thermodynamics and kinetics of the Schottky defect at terraces and steps on the MgO(001) surface
Ekaterina Antoshchenkova1, Marc Hayoun, Grégory Geneste
1Laboratoire des Solides Irradiés, Ecole Polytechnique, CEA-DSM, CNRS, 91128 Palaiseau, France. ekaterina.antoshchenkova@polytechnique.edu
Abstract:
The Schottky defects at both the flat MgO(001) surface and the monatomic-step edge have been investigated by equilibrium molecular dynamics simulations. The formation enthalpy as a function of the distance between the Mg and O vacancies that form a Schottky defect have been calculated and discussed. We conclude that a step edge is a stable location for a vacancy. The migration mechanism has been elucidated and an intermediate state has been identified. The associated activation enthalpies have been determined in the 700-1100 K temperature range. Both magnesium and oxygen vacancies at the surface are very mobile and can play a role during the crystal growth.
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