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Related Concept Videos

Emission Spectra02:39

Emission Spectra

When solids, liquids, or condensed gases are heated sufficiently, they radiate some of the excess energy as light. Photons produced in this manner have a range of energies, and thereby produce a continuous spectrum in which an unbroken series of wavelengths is present.
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used.
NMR Spectroscopy: Chemical Shift Overview01:15

NMR Spectroscopy: Chemical Shift Overview

The position of the absorption signal of a sample is reported relative to the position of the signal of tetramethylsilane (TMS), which is added as an internal reference while recording spectra. The difference between the absorption frequencies of the sample and TMS (in Hz) is divided by the spectrometer operating frequency (in MHz) to obtain a dimensionless quantity called the chemical shift. It is reported on the δ (delta) scale and expressed in parts per million.
For instance, the proton...
IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations01:08

IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations

Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these vibrations also influence the shape of the IR peak. Generally, asymmetric stretching frequencies are higher than symmetric stretching frequencies. For example, primary amines exhibit two distinct IR peaks between 3300–3500 cm−1 corresponding to the symmetric and asymmetric N-H stretching, while secondary amines exhibit a single stretching vibration...
Atomic Emission Spectroscopy: Instrumentation01:22

Atomic Emission Spectroscopy: Instrumentation

The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...

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Related Experiment Video

Updated: Jun 12, 2026

Angle-resolved Photoemission Spectroscopy At Ultra-low Temperatures
08:53

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Published on: October 9, 2012

Spectral line tilt effect in the Ebert spectrograph.

R Trawinski, A Bielski, R S Dygdala

    Applied Optics
    |May 22, 2010
    PubMed
    Summary

    Spectral lines tilt away from the normal on photographic plates in Ebert spectrographs when the grating rotates. This study calculates this spectral line tilt effect and compares it with experimental data.

    Area of Science:

    • Spectroscopy
    • Optical Physics
    • Astronomy Instrumentation

    Background:

    • Ebert spectrographs are used for high-resolution spectral analysis.
    • Understanding spectral line behavior is crucial for accurate measurements.
    • Grating rotation can introduce optical aberrations.

    Purpose of the Study:

    • To calculate the spectral line tilt effect in Ebert spectrographs.
    • To compare theoretical calculations with experimental observations.
    • To validate the understanding of optical physics in spectrographic instrumentation.

    Main Methods:

    • Theoretical calculation of spectral line tilt based on Ebert spectrograph geometry.
    • Experimental setup to measure spectral line positions on photographic plates.

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  • Comparison of calculated tilt angles with measured tilt angles.
  • Main Results:

    • The study successfully calculated the spectral line tilt effect.
    • Calculated values showed good agreement with experimental data.
    • The observed tilt is a direct consequence of grating rotation.

    Conclusions:

    • The theoretical model accurately predicts the spectral line tilt in Ebert spectrographs.
    • Experimental validation confirms the calculated effect.
    • This work enhances the understanding of spectrograph performance and calibration.