Related Experiment Video
Updated: Jun 12, 2026

09:50
Biosynthesis of a Flavonol from a Flavanone by Establishing a One-pot Bienzymatic Cascade
Published on: August 14, 2019
Flavonol glycosides with alpha-D-aldohexoses from Rhododendron irroratum
Ming Hua Yang1, Jian Guang Luo, Xue Feng Huang
1Department of Natural Medicinal Chemistry, China Pharmaceutical University, Nanjing, PR China.
Natural Product Research
|May 25, 2010
Abstract:
Two new flavonol glycosides which contain rare alpha-D-galactose or alpha-D-glucose were obtained from the flowers of Rhododendron irroratum Franch., namely myricetin 3-O-beta-D-galactoside-3'-O-alpha-D-glucoside (1) and myricetin 3-O-beta-D-galactoside-3'-O-alpha-D-galactoside (2). Their structures were determined by UV, IR, HR-ESI-MS, ESI-MS, 1D- and 2D-NMR techniques.
Related Concept Videos
Oxidation of Phenols to Quinones
In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
Red Algae
Red algae, also known as rhodophytes, are primarily found in marine environments, though some species inhabit freshwater and terrestrial ecosystems. These organisms exist in both unicellular and multicellular forms, with some multicellular varieties reaching macroscopic sizes.As phototrophic organisms, red algae contain chlorophyll a; however, their chloroplasts lack chlorophyll b. Instead, they possess phycobiliproteins, which serve as major light-harvesting pigments, similar to those found in...
