[Effect of the change in fundamental Raman scattering coefficient with the concentration on Fermi resonance in binary...

The Raman scattering coefficients of the fundamental v1 (992 cm(-1)) of C6 H6 and the fundamental v1 (656 cm(-1) ) of CS2 changed dramatically with relative concentration of the binary solution of CS2 and C6 H6. The Raman spectra of the binary solution with different relative concentrations were measured. The results show that both the v1 fundamentals intensities changed dramatically with the relative concentration of the solution and the fundamental v1 of C6 H6 has little effect on the Fermi resonance v1 +v6-v8. On the contrary, the change in the v1 fundamental intensity of the CS2 changed which has more effect not only on the Fermi resonance v1 - 2v2 but also on the v2 fundamental. In this report, the experimental results were analyzed based on the J. F. Bertran theory and group theory.