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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Transient chirality in a distal-substituted resorcinarene metal complex

Dewald J Kleinhans1, Gareth E Arnott

  • 1Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland, 7602, South Africa.

Dalton Transactions (Cambridge, England : 2003)
|May 29, 2010
PubMed
Summary

Researchers synthesized a novel resorcinarene ligand and a palladium complex, revealing the first crystal structure of a bispalladium-mu-chloro-bridged complex with thioether ligands. Solution studies indicated ligand flexibility and transient chirality at sulfur centers.

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