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A Customizable Approach for the Enzymatic Production and Purification of Diterpenoid Natural Products
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Published on: October 4, 2019

A biochemical interpretation of terpene chemotypes in Melaleuca alternifolia

Andras Keszei1, Yasmin Hassan, William J Foley

  • 1Research School of Biology, Australian National University, Canberra 0200, Australia. andras.keszei@anu.edu.au

Journal of Chemical Ecology
|May 29, 2010
PubMed

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Mass Spectrometry: Alkene Fragmentation

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This lesson delves into the mass spectrometry of branched alkane fragmentation. Branched alkanes possess secondary or tertiary carbon atoms, which generate relatively stable carbocations if the cleavage occurs at the branching point. The high stability of carbocations drives the instant fragmentation of branched alkanes. Accordingly, the branched alkane's molecular ion peak is very weak or invisible in the mass spectra, especially in comparison to a linear alkane.
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