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Related Concept Videos

Phase Diagrams of Ternary Systems01:28

Phase Diagrams of Ternary Systems

Consider a ternary system, which is composed of three components: water (W), ethanoic acid (E), and trichloromethane (T). Here, Ethanoic acid (E) is fully miscible with both water (W) and trichloromethane (T), meaning it can mix entirely with either of them. However, water and trichloromethane have partial miscibility, meaning they can only mix to a certain extent, beyond which two separate phases will form.The phase diagram of a ternary system is represented as an equilateral triangle, where...
Aromatic Hydrocarbon Cations: Structural Overview01:18

Aromatic Hydrocarbon Cations: Structural Overview

Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
Removing one hydrogen from the intervening CH2 group with both...
Properties of Transition Metals02:58

Properties of Transition Metals

Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
Colors and Magnetism03:02

Colors and Magnetism

Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Types of Semiconductors01:20

Types of Semiconductors

Intrinsic semiconductors are highly pure materials with no impurities. At absolute zero, these semiconductors behave as perfect insulators because all the valence electrons are bound, and the conduction band is empty, disallowing electrical conduction. The Fermi level is a concept used to describe the probability of occupancy of energy levels by electrons at thermal equilibrium. In intrinsic semiconductors, the Fermi level is positioned at the midpoint of the energy gap at absolute zero. When...
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...

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Related Experiment Video

Updated: Jun 12, 2026

Demonstrating the Simplicity and In Situ Temperature Monitoring of the Mechanochemical Synthesis of Metal Chalcogenides Suitable for Thermoelectrics
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Tunable multifunctional topological insulators in ternary Heusler compounds.

Stanislav Chadov, Xiaoliang Qi, Jürgen Kübler

    Nature Materials
    |June 1, 2010
    PubMed
    Summary

    Researchers discovered over 50 Heusler compounds exhibiting topological properties similar to HgTe. These materials offer tunable bandgaps and spin-orbit coupling for novel quantum states.

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    Area of Science:

    • Condensed-matter physics
    • Materials science
    • Quantum mechanics

    Background:

    • The quantum spin Hall effect, a novel quantum state, has been realized in HgTe quantum wells.
    • Topological insulators are states of quantum matter with significant implications for physics and materials science.
    • Heusler compounds, structurally related to binary semiconductors, offer diverse electronic properties.

    Discussion:

    • First-principle calculations reveal that approximately 50 Heusler compounds exhibit band inversion akin to HgTe.
    • Topological states in these zero-gap semiconductors can be induced via strain or quantum-well engineering.
    • The presence of rare-earth elements in many Heusler compounds introduces additional functionalities like superconductivity and magnetism.

    Key Insights:

    • Identification of numerous Heusler compounds as potential topological materials.
    • Demonstration of methods to create topological states in these compounds.
    • Highlighting the role of rare-earth elements in expanding material properties.

    Outlook:

    • Exploration of Heusler compounds for quantized anomalous Hall effect realization.
    • Investigating topological superconductors based on these materials.
    • Leveraging combined topological and rare-earth properties for advanced quantum devices.