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Infrared (IR) Spectroscopy: Overview01:09

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When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
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There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...

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Related Experiment Video

Updated: Jun 12, 2026

Determination of the Excitation and Coupling Rates Between Light Emitters and Surface Plasmon Polaritons
07:39

Determination of the Excitation and Coupling Rates Between Light Emitters and Surface Plasmon Polaritons

Published on: July 21, 2018

Long-wave infrared surface plasmon grating coupler.

Justin W Cleary1, Gautam Medhi, Robert E Peale

  • 1Department of Physics, University of Central Florida, Orlando, Florida 32816, USA.

Applied Optics
|June 3, 2010
PubMed
Summary

We developed a simple formula to design gratings for coupling long-wave infrared light to surface plasmons. The optimal grating depth for this energy conversion is 10%-15% of the wavelength.

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Last Updated: Jun 12, 2026

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Area of Science:

  • Optics and Photonics
  • Materials Science

Background:

  • Coupling light to surface plasmons is crucial for various photonic applications.
  • Designing efficient gratings for long-wave infrared (LWIR) radiation presents unique challenges.

Purpose of the Study:

  • To present a simplified analytic formula for designing gratings to couple LWIR radiation to surface plasmons.
  • To determine the optimal grating parameters for efficient photon-to-surface-plasmon energy conversion.

Main Methods:

  • The study utilizes a semiempirical approach based on Hessel and Oliner's theory.
  • It involves finding the surface-impedance modulation amplitude as a function of grating groove depth and wavelength.
  • Experiments and calculations were performed for silver lamellar gratings at CO(2) laser wavelengths.

Main Results:

  • A simplified analytic formula for grating design is presented.
  • The optimum groove depth for photon-to-surface-plasmon energy conversion was determined to be approximately 10%-15% of the wavelength.
  • This optimal depth is significantly larger than previously reported for visible spectral ranges.

Conclusions:

  • The developed formula offers a practical tool for designing LWIR-to-surface-plasmon coupling gratings.
  • The findings provide guidance on optimizing grating geometry for enhanced energy conversion efficiency in the infrared spectrum.