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Dimeric versus polymeric coordination in copper(II) cationic complexes with bis(chelating) oxime and amide ligands

Andrii I Buvailo1, Elzbieta Gumienna-Kontecka, Svetlana V Pavlova

  • 1Department of Chemistry, National Taras Shevchenko University, 01601, Kiev, Ukraine.

Dalton Transactions (Cambridge, England : 2003)
|June 4, 2010
PubMed
Summary

New copper(II) complexes were synthesized using novel oxime and amide ligands. Dimeric structures were favored over polymeric ones due to stabilizing intramolecular hydrogen bonds, demonstrating supramolecular isomerism.

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