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Related Concept Videos

Atomic Emission Spectroscopy: Lab01:29

Atomic Emission Spectroscopy: Lab

AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...
Atomic Emission Spectroscopy: Overview01:20

Atomic Emission Spectroscopy: Overview

Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
Atomic Fluorescence Spectroscopy01:29

Atomic Fluorescence Spectroscopy

Atomic fluorescence spectroscopy (AFS) is an analytical technique that involves the electronic transitions of atoms in a flame, furnace, or plasma being excited by electromagnetic (EM) radiation. When these atoms absorb energy, they become excited and subsequently release energy as they return to their original state. This emitted light, or "fluorescence," is observed at a right angle to the incident beam. Both absorption and emission processes transpire at distinct wavelengths, which are...
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used.
Atomic Spectroscopy: Absorption, Emission, and Fluorescence01:23

Atomic Spectroscopy: Absorption, Emission, and Fluorescence

Atomic spectroscopy is a vital tool in elemental analysis, both qualitatively and quantitatively. It can be broadly divided into optical spectroscopy, mass spectroscopy, and X-ray spectroscopy methods. The optical spectroscopic methods are atomic absorption spectroscopy (AAS), atomic emission spectroscopy (AES), and atomic fluorescence spectroscopy (AFS). The first step in all three methods is atomization, where the solid, liquid, or solution-phase samples are converted into gas-phase atoms and...
Tandem Mass Spectrometry01:21

Tandem Mass Spectrometry

Tandem mass spectrometry is a technique that uses multiple mass analyzers in series to obtain a higher selectivity and reduce chemical noise during analyte detection. Instruments with multiple analyzers separated by an interaction cell enable secondary fragmentation and selected study of the fragment ions.Secondary fragmentations occur in the interaction cell and can be induced by various factors. Fragmentation induced by collision with inert gases, such as N2, Ar, He, etc., is called...

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A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
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Application of parallel factor analysis for time-resolved laser fluorescence spectroscopy: implication for metal

Takumi Saito1, Hirokazu Sao, Keisuke Ishida

  • 1Department of Nuclear Engineering and Management, School of Engineering, The University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan. takumi@flanker.n..t.u-tokyo.ac.jp

Environmental Science & Technology
|June 10, 2010
PubMed
Summary

Time-resolved laser fluorescence spectroscopy (TRLFS) aids in identifying metal ion species. Applying parallel factor analysis (PARAFAC) to TRLFS data simplifies extracting crucial speciation information for fluorescent metal ions.

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Area of Science:

  • Analytical Chemistry
  • Spectroscopy
  • Chemometrics

Background:

  • Time-resolved laser fluorescence spectroscopy (TRLFS) is vital for differentiating fluorescent metal ion species.
  • Extracting quantitative and structural data from complex TRLFS datasets is challenging.

Purpose of the Study:

  • To apply parallel factor analysis (PARAFAC) for interpreting complex TRLFS data.
  • To demonstrate PARAFAC's utility in metal ion speciation studies.

Main Methods:

  • Utilized PARAFAC, a multiway data analysis technique.
  • Applied PARAFAC to a TRLFS dataset of Europium(III) complexation with acetate.

Main Results:

  • PARAFAC successfully decomposed the TRLFS data, identifying three essential factors.
  • The derived factor spectra, decay times, and concentrations align with known Eu(3+)-acetate complexation behavior.

Conclusions:

  • PARAFAC is a powerful and promising tool for analyzing TRLFS data.
  • This method enhances the speciation studies of fluorescent metal ions like lanthanides and actinides.