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Phosphine-free synthesis of p-type copper(I) selenide nanocrystals in hot coordinating solvents

Sasanka Deka1, Alessandro Genovese, Yang Zhang

  • 1Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy.

Journal of the American Chemical Society
|June 15, 2010
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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.