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Updated: Jun 12, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
From well-defined macromonomers to sterically-stabilised latexes to covalently cross-linkable colloidosomes: exerting
Kate L Thompson1, Steven P Armes
1Dainton Building, Department of Chemistry, The University of Sheffield Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK.
Abstract:
A new route to covalently cross-linkable colloidosomes has been developed via the assembly of sterically stabilised latex particles onto oil droplets. These latexes can be cross-linked from within the oil droplets via the steric stabiliser chains on the inner-particle surface using an oil-soluble polymeric diisocyanate. Such microcapsules can survive both surfactant and alcohol challenges.
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