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Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
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Synthesis and characterisation of the persistent radical [BCl2(bipy)]*

Stephen M Mansell1, Christopher J Adams, George Bramham

  • 1School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.

Chemical Communications (Cambridge, England)
|June 17, 2010
PubMed
Summary

Researchers synthesized and characterized a stable boron-containing radical, [BCl(2)(bipy)](*), using X-ray crystallography, ESR, and DFT. Its structure was compared to the related cation, [BCl(2)(bipy)](+).

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