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Updated: Jun 12, 2026

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TiO2-coated Hollow Glass Microspheres with Superhydrophobic and High IR-reflective Properties Synthesized by a Soft-chemistry Method
Published on: April 26, 2017
Rewritable superhydrophilic-superhydrophobic patterns on a sintered titanium dioxide substrate
Kazuya Nakata1, Shunsuke Nishimoto, Yumi Yuda
1Photocatalyst group, Kanagawa Academy of Science and Technology, KSP West 614, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012, Japan.
Langmuir : the ACS Journal of Surfaces and Colloids
|June 18, 2010
Summary
Researchers developed a novel method for creating tunable superhydrophilic-superhydrophobic patterns on titanium dioxide (TiO2) surfaces. This eco-friendly process utilizes inkjet printing and photocatalytic decomposition, offering a renewable approach for surface wettability control.
Area of Science:
- Materials Science
- Surface Chemistry
- Nanotechnology
Background:
- Controlling surface wettability is crucial for various applications.
- Existing methods for creating wettability patterns can be complex and resource-intensive.
Purpose of the Study:
- To develop a new, environmentally friendly fabrication process for superhydrophilic-superhydrophobic patterns on TiO2 surfaces.
- To demonstrate the renewable and site-selective nature of the patterning technique.
Main Methods:
- Utilized inkjet printing to deposit self-assembled monolayers (SAMs).
- Employed site-selective photocatalytic decomposition of SAMs on a TiO2 surface using UV irradiation.
- Surface morphology was induced by calcination of a Ti substrate.
Main Results:
- Successfully fabricated superhydrophilic-superhydrophobic patterns on TiO2 surfaces.
- Demonstrated regeneration of the TiO2 substrate after pattern removal.
- Achieved deposition of new patterns with distinct characteristics on the regenerated surface.
Conclusions:
- The described process offers a renewable, resource-saving, and environmentally friendly method for creating wettability patterns.
- The technique allows for the creation of tunable and reproducible surface patterns.
- The photocatalytic decomposition and regeneration mechanism provides a versatile platform for surface modification.

