Related Experiment Video
Updated: Jun 12, 2026

09:32
Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films
Published on: January 26, 2016
Buchdahl's glass dispersion coefficients calculated from Schott equation constants
Applied Optics
|June 18, 2010
Summary
This study presents a new method for quickly calculating Buchdahl
Area of Science:
- Optical Engineering
- Materials Science
- Computational Physics
Background:
- Accurate modeling of optical materials is crucial for lens design.
- Schott and Buchdahl dispersion models are widely used but can be complex to evaluate.
- Evaluating dispersion coefficients at arbitrary wavelengths is computationally intensive.
Purpose of the Study:
- To develop a rapid method for evaluating Buchdahl's dispersion coefficients.
- To enable calculations at any arbitrary base wavelength using Schott equation constants.
- To simplify the application of Buchdahl's dispersion model in optical design.
Main Methods:
- Applied Buchdahl's chromatic coordinate transformation to the Schott equation for refractive index.
- Utilized a Taylor series expansion of the transformed Schott equation.
- Equated the expansion to the square of the Buchdahl dispersion model and matched terms up to fourth order.
Main Results:
- Derived analytical equations for Buchdahl's dispersion coefficients.
- The method allows for efficient calculation at any specified base wavelength.
- Validated the accuracy of the derived coefficients against established models.
Conclusions:
- The presented method offers a computationally efficient approach to determine Buchdahl's dispersion coefficients.
- This facilitates faster optical design and analysis using the Schott and Buchdahl dispersion models.
- The technique is broadly applicable for optical materials characterization.
More Related Videos
Related Concept Videos
Debye–Huckel–Onsager Conductance Equation
The Debye-Hückel-Onsager equation is a cornerstone of physical chemistry, providing a method to determine the molar conductance (Λm) and molar conductance at infinite dilution (Λ°m) for uni-univalent electrolytes.Uni-univalent electrolytes are electrolytes that dissociate in solution to produce one cation with a +1 charge and one anion with a –1 charge per formula unit.This equation addresses two crucial phenomena: the asymmetry effect and the electrophoretic effect. According to this equation,...
Extraction: Partition and Distribution Coefficients
The distribution law or Nernst's distribution law is the law that governs the distribution of a solute between two immiscible solvents. This law, also known as the partition law, states that if a solute is added to the mixture of two immiscible solvents at a constant temperature, the solute is distributed between the two solvents in such a way that the ratio of solute concentrations in the solvents remains constant at equilibrium.
For extracting a solute from an aqueous phase into an organic...
For extracting a solute from an aqueous phase into an organic...
Kohlraush’s Law and its Applications
Kohlrausch's law explains that at infinite dilution, where dissociation is complete, each ion's contribution to the conductivity of the electrolyte is independent of the nature of other ions present in the solution. It also implies that when an electrolyte is highly diluted, the conductance of the electrolyte is the sum of the individual conductances of the ions it generates upon dissociation. The quantity of electricity an ion carries is proportional to its molar ionic conductance, which...
Imperfections in Crystal Structure: Stoichiometric Point Defects
Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...
Glassware Calibration
Accurate calibration of glassware, such as volumetric flasks, pipettes, and burettes, is essential to ensure accurate measurements in the analytical laboratory. Calibration helps maintain consistency across measurements and prevents errors arising from inaccurate volumes.
Volumetric flasks: Volumetric flasks are designed to prepare aqueous solutions of precise volumes accurately with a calibration line on the neck. To calibrate a volumetric flask, it is important to fill it with distilled...
Volumetric flasks: Volumetric flasks are designed to prepare aqueous solutions of precise volumes accurately with a calibration line on the neck. To calibrate a volumetric flask, it is important to fill it with distilled...
Ostwald’s Dilution Law
Consider a binary electrolyte AB with a concentration ‘c’ that reversibly dissociates into its constituent ions. The degree of this dissociation is represented by ⍺. This means that the equilibrium concentration of each ionic species can be expressed as ⍺c. As well as this, the fraction of the electrolyte that remains undissociated at equilibrium is given by (1−⍺). The corresponding equilibrium concentration for this undissociated portion is then calculated as (1−⍺)c. For such solutions,...

