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Updated: Jun 12, 2026

Synthesis and Reaction Chemistry of Nanosize Monosodium Titanate
Published on: February 23, 2016
Synthesis of TiO2 nanocrystals with a high affinity for amine organic compounds
Ricardo H Gonçalves1, Wido Herwig Schreiner, Edson R Leite
1Department of Chemistry, Federal University of São Carlos, 13565-905 São Carlos, SP, Brazil.
Abstract:
This article describes a different approach to the colloidal synthesis of TiO(2) nanocrystals using a polymer melt as a solvent. This approach allowed us to obtain a colloidal dispersion with a high degree of stability in a polymeric solvent, resulting in a transparent colloid. Using this method, it was possible to obtain the TiO(2) nanocrystal with Brønsted acid sites and polymer chains chemically anchored on the nanocrystal surface. The acid surface of those nanocrystals has the chemical property to react in the presence of amine organic compounds and to maintain the colloidal stability. In this way, TiO(2) nanocrystals were combined with a molecular probe containing amine functional groups such as polyaniline. Through the combination of the molecular probe and inorganic nanocrystals, we obtained a hybrid material with interesting chemical, optical, and electronic behavior, making it a promising material for photovoltaic, photochromic, and sensor devices.
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