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Classification and Mechanical Properties of Synthetic Polymers01:28

Classification and Mechanical Properties of Synthetic Polymers

Synthetic polymers are classified as elastomers, fibers, or plastics based on their crystallinity. Crystallinity, the degree of long-range order in the solid state, influences the mechanical properties (stretching or contracting) of elastomers. Elastomers are flexible polymers that can expand or contract easily upon the application of an external force. They have numerous crosslinks that pull them back into their original shape when stress is removed. Silicones, for instance, are highly elastic...
Polymer Classification: Architecture01:14

Polymer Classification: Architecture

Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
Characteristics and Nomenclature of Copolymers01:24

Characteristics and Nomenclature of Copolymers

Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
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Molecular Weight of Step-Growth Polymers

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the properties that they exhibit. Additionally,...

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Shape Memory Polymers for Active Cell Culture
10:53

Shape Memory Polymers for Active Cell Culture

Published on: July 4, 2011

Multifunctional shape-memory polymers.

Marc Behl1, Muhammad Yasar Razzaq, Andreas Lendlein

  • 1Center of Biomaterial Development, Institute of Polymer Research, Teltow, Germany.

Advanced Materials (Deerfield Beach, Fla.)
|June 25, 2010
PubMed
Summary
This summary is machine-generated.

Shape-memory polymers (SMP) offer programmable shape changes via heat. This review explores creating multifunctional SMP by integrating additional properties into polymer networks for advanced applications.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Smart Materials

Background:

  • Thermally-induced shape-memory effect (SME) enables materials to recover programmed shapes upon heating.
  • Shape-memory polymers (SMP) utilize entropy-driven recovery of deformation fixed by physical crosslinks.
  • SMP have diverse applications in packaging, textiles, biomedical, and aerospace industries.

Purpose of the Study:

  • To review concepts for creating multifunctional shape-memory polymers (SMP).
  • To explore integration of additional functions into SMP beyond shape memory.
  • To discuss challenges and future directions in multifunctional SMP development.

Main Methods:

  • Review of polymer network architectures for thermally-induced SMP.
  • Analysis of multimaterial systems, including nanocomposites.
  • Examination of one-component polymer systems with integrated functions.

Main Results:

  • Different strategies for achieving multifunctionality in SMP are presented.
  • Multifunctional SMP can be created through various polymer network designs.
  • Both multimaterial and one-component systems offer pathways to enhanced SMP.

Conclusions:

  • Multifunctional SMP are crucial for meeting complex application demands.
  • Future research should focus on integrating multifunctionality into emerging shape-memory technologies.
  • Expanding SMP capabilities to light-sensitive, reversible, and triple-shape effects is a key challenge.