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Updated: Jun 11, 2026

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Nonlinear spectroscopic properties of Yb3+-doped sesquioxides Lu2O3 and Sc2O3
R Soulard1, R Moncorgé, A Zinoviev
1Centre de Recherche sur les Ions, les Matériaux et la Photonique (CIMAP), UMR 6252 CNRS-CEA-ENSICAEN, Université de Caen, France.
Abstract:
We report on the measurements of near-UV excited-state absorption (ESA) spectra and refractive index changes (RICs) in the two ytterbium doped laser crystals Yb:Lu2O3 and Yb:Sc2O3. ESA is assigned to ligand-to-metal charge transfer (LMCT) absorption transitions and RICs to the polarizability changes experienced by the Yb3+ ions due to these strong electric-dipole allowed absorption bands.
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