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Related Concept Videos

Tandem Mass Spectrometry01:21

Tandem Mass Spectrometry

Tandem mass spectrometry is a technique that uses multiple mass analyzers in series to obtain a higher selectivity and reduce chemical noise during analyte detection. Instruments with multiple analyzers separated by an interaction cell enable secondary fragmentation and selected study of the fragment ions.Secondary fragmentations occur in the interaction cell and can be induced by various factors. Fragmentation induced by collision with inert gases, such as N2, Ar, He, etc., is called...
Interpreting ¹H NMR Signal Splitting: The (n + 1) Rule01:10

Interpreting ¹H NMR Signal Splitting: The (n + 1) Rule

In the AX proton spin system, proton A can sense the two spin states of a coupled proton X, resulting in a doublet NMR signal with two peaks of equal (1:1) intensity. When proton A is coupled to two equivalent protons (AX2 spin system), the spin states of each X can be aligned with or against the external field, creating three possible scenarios. This results in a 1:2:1  triplet signal, where the central peak corresponds to the chemical shift of A and is twice as large or intense as the others.
¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)01:20

¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)

When proton-coupled carbon-13 spectra are simplified by a broadband proton decoupling technique, structural information about the coupled protons is lost. Distortionless enhancement by polarization transfer (DEPT) is a technique that provides information on the number of hydrogens attached to each carbon in a molecule. While the DEPT experiment utilizes complex pulse sequences, the pulse delay and flip angle are specifically manipulated. The resulting signals have different phases depending on...
Double Resonance Techniques: Overview01:12

Double Resonance Techniques: Overview

Double resonance techniques in Nuclear Magnetic Resonance (NMR) spectroscopy involve the simultaneous application of two different frequencies or radiofrequency pulses to manipulate and observe two distinct nuclear spins. One important application of double resonance is spin decoupling, which selectively suppresses coupling with one type of nucleus while observing the NMR signal from another nucleus, simplifying the spectrum and enhancing resolution.
Spin decoupling is usually achieved by...
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
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Mass Analyzers: Common Types01:19

Mass Analyzers: Common Types

The quadrupole mass analyzer consists of four cylindrical metal rods arranged in a diamond carrying a DC voltage and a radio-frequency AC voltage. The motion of ions through the quadrupole depends on the field strength, causing only ions of a certain m/z to resonate successfully and strike the detector at a given field strength. Though the transmission rate for these analyzers is high, the exact elemental composition of the sample is not determined because of low resolution; however, they are...

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A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference

Published on: September 5, 2019

Multidimensional pump-probe spectroscopy with entangled twin-photon states.

Oleksiy Roslyak1, Shaul Mukamel

  • 1Department of Chemistry, University of California, Irvine, California 92697-2025, USA.

Physical Review. A, Atomic, Molecular, and Optical Physics
|July 8, 2010
PubMed
Summary

Entangled photons enable novel coherent multidimensional nonlinear spectroscopy by scanning photon wave function parameters. This technique offers high temporal resolution for studying matter correlations and dynamics.

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Area of Science:

  • Quantum Optics
  • Nonlinear Spectroscopy
  • Spectroscopic Techniques

Background:

  • Classical multidimensional nonlinear spectroscopy commonly uses frequencies and time delays.
  • Scanning photon wave function parameters offers an alternative approach to probing matter.

Purpose of the Study:

  • To demonstrate the use of entangled photons in coherent multidimensional nonlinear spectroscopy.
  • To explore novel methods for obtaining information on matter using quantum properties of light.

Main Methods:

  • Utilizing entangled photons instead of classical pulses for spectroscopy.
  • Employing a diagrammatic close time path loop formalism for signal interpretation.
  • Scanning entanglement time and delay of twin photons as spectroscopic parameters.

Main Results:

  • Entangled photons provide information on matter by scanning entanglement time and twin photon delay.
  • Two-photon resonant contributions scale linearly with incident intensity, revealing off-resonant transition frequencies.
  • Two-dimensional spectrograms offer high temporal resolution for correlations and dynamics.

Conclusions:

  • Entangled photon spectroscopy provides a new pathway for investigating quantum correlations and dynamics.
  • This method offers an alternative to classical pulse shaping techniques in multidimensional spectroscopy.