Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Discovery of novel perillyl and myrtenyl nucleobase conjugates as dual anti-Alzheimer and antimicrobial agents.

Molecular diversity·2026
Same author

Deciphering unusually large modulations in two related organic hydroxy channel structures.

Acta crystallographica Section B, Structural science, crystal engineering and materials·2026
Same author

Metal-Free Active Template: A Straightforward Route to 4-Aminopyridinium-Based Rotaxane Molecular Shuttles.

Angewandte Chemie (International ed. in English)·2026
Same author

Selective Nitrate Transmembrane Transport Through Adaptive Weak C─H Bonding Cyanostilbene Water Channels.

Angewandte Chemie (International ed. in English)·2026
Same author

2-Quinolone-1,2,3-triazole-benzofuran-N-acylhydrazone hybrids as antiviral and antimicrobial agents: synthesis, in vitro screening and molecular modeling.

Molecular diversity·2026
Same author

Synthesis and Comparison of the Flame-Retardant Properties of Phosphorylated-Coumarins and Phosphorylated-Isophosphinolines.

Molecules (Basel, Switzerland)·2025

Related Experiment Video

Updated: Jun 11, 2026

Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies
09:38

Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies

Published on: January 3, 2018

Selective lanthanides sequestration based on a self-assembled organosilica.

Eric Besson1, Ahmad Mehdi, Arie Van der Lee

  • 1Institut de chimie séparative de Marcoule, UMR 5257, ICSM Site de Marcoule, BP 17171, 30207 Bagnols sur Cèze Cedex, France.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|July 8, 2010
PubMed
Summary

This study explores a novel hybrid material for capturing trivalent ions like lanthanides and iron. The material demonstrates selective cation exchange, offering potential applications in separation and purification processes.

More Related Videos

A Dual-Functional Electroactive Filter Towards Simultaneously Sb(III) Oxidation and Sequestration
08:34

A Dual-Functional Electroactive Filter Towards Simultaneously Sb(III) Oxidation and Sequestration

Published on: December 5, 2019

Preparation of Functional Silica Using a Bioinspired Method
08:04

Preparation of Functional Silica Using a Bioinspired Method

Published on: August 1, 2018

Related Experiment Videos

Last Updated: Jun 11, 2026

Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies
09:38

Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies

Published on: January 3, 2018

A Dual-Functional Electroactive Filter Towards Simultaneously Sb(III) Oxidation and Sequestration
08:34

A Dual-Functional Electroactive Filter Towards Simultaneously Sb(III) Oxidation and Sequestration

Published on: December 5, 2019

Preparation of Functional Silica Using a Bioinspired Method
08:04

Preparation of Functional Silica Using a Bioinspired Method

Published on: August 1, 2018

Area of Science:

  • Materials Science
  • Inorganic Chemistry
  • Nanotechnology

Background:

  • Self-assembled hybrid materials offer unique properties for ion exchange.
  • Trivalent ions, particularly lanthanides and iron, are crucial in various industrial and scientific applications.
  • Developing selective materials for trivalent ion separation remains a challenge.

Purpose of the Study:

  • To investigate the cation-exchange capabilities of a novel bis-zwitterionic lamellar hybrid material.
  • To evaluate the material's selectivity towards trivalent lanthanide ions (La(3+), Eu(3+), Gd(3+), Yb(3+)) and Fe(3+).
  • To elucidate the ion-exchange mechanism and propose a structural model for ion incorporation.

Main Methods:

  • Sol-gel synthesis using 3-aminopropyltriethoxysilane (APTES), succinic anhydride, and ethylenediamine.
  • Cation-exchange experiments in ethanol and aqueous solutions.
  • Complexometry, elemental analyses, X-ray diffraction (XRD), and Mössbauer spectroscopy for material characterization.

Main Results:

  • Complete exchange of ethylenediammonium ions with lanthanide ions (Ln(3+)) was achieved.
  • The material exhibited selectivity towards lanthanides, with cation uptake varying based on salt nature and lanthanide type.
  • Mössbauer spectroscopy and XRD analysis provided insights into the structural incorporation of trivalent ions.

Conclusions:

  • The self-assembled hybrid material demonstrates effective and selective cation-exchange properties for trivalent ions.
  • The findings suggest potential applications in lanthanide and iron ion separation and purification.
  • A structural model for trivalent ion incorporation via ion exchange was proposed.