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Potential Due to a Polarized Object01:29

Potential Due to a Polarized Object

A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
Continuous Charge Distributions01:17

Continuous Charge Distributions

Imagine a bucket of water. It contains many molecules, of the order of 1026 molecules. Thus, although it contains discrete elements (molecules) at the microscopic level, macroscopically, it can be considered continuous. Small volume elements of water, infinitesimal compared to the bulk of the bucket's volume, still contain many molecules. Under this framework, quantized matter is approximated as continuous for practical purposes.
The electric charge can also be subjected to an analogical...
The Electrical Double Layer01:30

The Electrical Double Layer

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
Electric Field of Two Equal and Opposite Charges01:30

Electric Field of Two Equal and Opposite Charges

Atoms generally contain the same number of positively and negatively charged particles, protons, and electrons. Hence, they are electrically neutral. However, the centers of the positive and negative charges do not always coincide. In such a scenario, the electric field of an atom may not be zero.
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...
Susceptibility, Permittivity and Dielectric Constant01:26

Susceptibility, Permittivity and Dielectric Constant

When placed in an external electric field, a dielectric material gets polarized. The charge density in the dielectric material is given by the sum of the bound and free charge densities, while the total charge density can also be written in terms of the total electric field. The bound charge density can be measured in terms of polarization, leading to the relationship between electric displacement and polarization.
Energy Associated With a Charge Distribution01:21

Energy Associated With a Charge Distribution

The work done to bring a charge through a distance r is given by the potential difference between the initial and the final position. To assemble a collection of point charges, the total work done can be expressed in terms of the product of each pair of charges divided by their separation distance, defined with respect to a suitable origin. Solving this expression gives the energy stored in a point charge distribution.

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Related Experiment Video

Updated: Jun 11, 2026

Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
08:06

Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone

Published on: February 23, 2017

Extended space charge in concentration polarization.

Isaak Rubinstein1, Boris Zaltzman

  • 1Blaustein Institutes for Desert Research, Ben-Gurion University of the Negev, Sede Boqer Campus 84990, Israel.

Advances in Colloid and Interface Science
|July 13, 2010
PubMed
Summary
This summary is machine-generated.

This study explores ionic transport and fluid flow at solid/liquid interfaces, revealing how extended space charge layers influence phenomena like anomalous rectification and overlimiting conductance. These effects are probed using electrical impedance spectroscopy and harmonic perturbations.

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Last Updated: Jun 11, 2026

Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
08:06

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Published on: February 23, 2017

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Published on: August 22, 2017

Area of Science:

  • Electrochemistry
  • Physical Chemistry
  • Fluid Dynamics

Background:

  • Ionic current and fluid flow at solid/liquid interfaces are crucial in systems like electrodes and nano-channels.
  • Concentration polarization leads to current saturation in voltage-current curves.
  • Anomalous rectification and electroosmotic instability arise from extended space charge layers.

Purpose of the Study:

  • To review the characteristics of non-equilibrium electric double layers and extended space charge.
  • To explore methods for probing these layers, including electrical impedance spectroscopy and anomalous rectification.
  • To understand phenomena influenced by these interfacial layers.

Main Methods:

  • Analysis of voltage-current curves and concentration polarization.
  • Review of electrical impedance spectroscopy.
  • Investigation of harmonic voltage/current perturbations for linear and non-linear system response.
  • Examination of anomalous rectification effects.

Main Results:

  • Extended space charge layers significantly impact ionic transport and fluid flow at interfaces.
  • These layers explain diverse phenomena such as anomalous rectification and overlimiting conductance.
  • Electrical impedance spectroscopy and harmonic perturbations are effective probing methods.

Conclusions:

  • The formation of extended space charge layers is a key factor in various interfacial phenomena.
  • Understanding these layers is essential for controlling ionic transport and fluid behavior.
  • Advanced electrical methods allow for direct probing of these non-equilibrium interfacial structures.