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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Phenoxazine based units--synthesis, photophysics and electrochemistry
Anna Nowakowska-Oleksy1, Jadwiga Sołoducho, Joanna Cabaj
1Faculty of Chemistry, Wrocław University of Technology, Wrocław, Poland.
Abstract:
A few new phenoxazine-based conjugated monomers were synthesized, characterized, and successfully used as semiconducting materials. The phenoxazine-based oligomers have low ionization potentials or high-lying HOMO levels (~4.7 eV), which were estimated from cyclic voltammetry. Conjugated oligomers offer good film-forming, mechanical and optical properties connected with their wide application. These results demonstrate that phenoxazine-based conjugated mers are a promising type of semiconducting and luminescent structures able to be used as thin films in organic electronics.
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