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Related Experiment Video

Updated: Jun 11, 2026

Synthesis and Characterization of Supramolecular Colloids
09:26

Synthesis and Characterization of Supramolecular Colloids

Published on: April 22, 2016

Towards supramolecular engineering of functional nanomaterials: pre-programming multi-component 2D self-assembly at

Artur Ciesielski1, Carlos-Andres Palma, Massimo Bonini

  • 1Nanochemistry Laboratory, ISIS, Université de Strasbourg and CNRS (UMR 7006), 8 allée Gaspard Monge, 67000 Strasbourg, France.

Advanced Materials (Deerfield Beach, Fla.)
|July 14, 2010
PubMed
Summary

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This review explores supramolecular materials engineered with precision using reversible non-covalent interactions. These dynamic materials offer control over self-assembly for advanced functional properties.

Area of Science:

  • Materials Science
  • Supramolecular Chemistry
  • Nanotechnology

Background:

  • Supramolecular materials offer precise engineering via reversible non-covalent interactions.
  • These materials are termed constitutionally dynamic due to their constituent recognition and exchange capabilities.
  • Tailoring material properties depends on controlling the self-assembly of molecular modules.

Purpose of the Study:

  • To review the formation of 2D supramolecular architectures using three classes of weak interactions.
  • To highlight the role of scanning tunneling microscopy in characterizing these structures.
  • To emphasize the potential for creating advanced functional materials.

Main Methods:

  • Focus on van der Waals, metallo-ligand, and hydrogen bonding interactions.

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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

Published on: May 9, 2014

Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets
13:42

Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets

Published on: November 2, 2011

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Last Updated: Jun 11, 2026

Synthesis and Characterization of Supramolecular Colloids
09:26

Synthesis and Characterization of Supramolecular Colloids

Published on: April 22, 2016

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
08:09

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

Published on: May 9, 2014

Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets
13:42

Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets

Published on: November 2, 2011

  • Utilize scanning tunneling microscopy for sub-nanometer resolution imaging.
  • Design molecular modules with specific recognition sites and functional units.
  • Main Results:

    • Demonstration of sub-nanometer precision in forming ordered supramolecular structures.
    • Evidence of responsive multicomponent architectures with controlled geometries.
    • Successful self-assembly of complex 2D architectures from designed molecular modules.

    Conclusions:

    • Weak interactions are key to precise supramolecular assembly.
    • Scanning tunneling microscopy provides critical insights into material structure.
    • This approach enables the creation of sophisticated smart materials with novel properties.