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Updated: Jun 11, 2026

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Constructing Thioether/Vinyl Sulfide-tethered Helical Peptides Via Photo-induced Thiol-ene/yne Hydrothiolation
Published on: August 1, 2018
Thermodynamic Origin of Prolyl Peptide Bond Isomers
Eric S Eberhardt1, Stewart N Loh, Ronald T Raines
1Department of Biochemistry, University of Wisconsin, Madison, WI 53706-1569 USA.
Tetrahedron Letters
|July 15, 2010
Abstract:
The thermodynamic preference for the trans isomer of prolyl peptide bonds arises almost entirely from enthalpy in aqueous buffer and in toluene.
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