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Updated: Jun 10, 2026

Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
Published on: February 14, 2014
Electronic spectroscopy and electronic structure of diatomic CrC
Dale J Brugh1, Michael D Morse, Apostolos Kalemos
1Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, USA.
Abstract:
Optical spectra of jet-cooled diatomic CrC have been recorded in the near infrared region using resonant two-photon ionization spectroscopy combined with mass-selective detection of the resulting ions. Several weak transitions have been observed, along with one relatively strong band near 842 nm. Rotational resolution and analysis of this band confirms that the ground state is of (3)Sigma(-) symmetry. Ab initio calculations have been performed that demonstrate that the ground state is highly multiconfigurational in nature, with a leading configuration of 1sigma(2)2sigma(2)1pi(4)1delta(2) for the ten valence electrons. From the rotational analysis of the 842 nm (3)Sigma(-)<--X (3)Sigma(-) band, the derived spectroscopic constants of the ground and excited states for (52)Cr(12)C are B(0)"=0.659 97(49), lambda(0)"=6.74(24), gamma(0)"=-0.066(20), T(0)=11 870.7660(65), B'=0.608 29(39), lambda'=7.11(24), and gamma'=0.144(17) cm(-1). Here and throughout this article, 1sigma error limits are reported in parentheses. These rotational constants may be inverted to provide the bond lengths in the ground and excited states, r(0)"=1.6188(6) A and r'=1.6861(5) A, respectively. Ab initio calculations show that the upper state is the third state of (3)Sigma(-) symmetry.
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