One-electron standard reduction potentials of nitroaromatic and cyclic nitramine explosives

Minori Uchimiya1, Leonid Gorb, Olexandr Isayev

  • 1Environmental Laboratory, U.S. Army Engineer Research and Development Center, Vicksburg, MS 39180, USA. sophie.uchimiya@ars.usda.gov

Summary

This study determined one-electron standard reduction potentials (Eo(R-NO2/R-NO2-)) for explosives. Values decrease from nitroaromatics to nitramines, predicting environmental reductive transformation rates.

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