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Updated: Jun 10, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Eta2-porphyrin Ru(II) pi complexes
Shigeru Yamaguchi1, Hiroshi Shinokubo, Atsuhiro Osuka
1Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan.
Abstract:
Highly stable eta(2)-porphyrin Ru(II) pi complexes have been synthesized. The formation of the eta(2) pi bond has been facilitated through pi-pi stacking interactions between the porphyrin and the planar ligand on Ru. pi coordination of ruthenium to porphyrin results in dramatic changes in the aromaticity and electronic properties. These properties are controllable via fine-tuning of the ligand on ruthenium.
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