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Updated: Jun 10, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
An approach to bimetallic catalysts by ligand design
Josep M López-Valbuena1, Eduardo C Escudero-Adan, Jordi Benet-Buchholz
1Institute of Chemical Research of Catalonia (ICIQ), Avgda. Països Catalans 16, Tarragona, Spain.
Abstract:
New diphosphines based on benzofurobenzofuran and dibenzodioxocin backbones, forming exclusively bimetallic complexes were designed and synthesized. Depending on the ligand to metal ratio, face-to-face bimetallic complexes or syn-chloride bridged dimeric complexes were formed as main reaction products. The structures of the rhodium complexes of the new ligands 4, 7, 10, 13, 16 were established in solution by NMR, IR, and MS spectroscopy. The molecular structures of the syn-chloride bridged dimeric complexes [Rh(2)(CO)(2)(mu-Cl)(2)(4)] (22), [Rh(2)(CO)(2)(mu-Cl)(2)(10)] (24), and the face-to-face bimetallic complexes [Rh(CO)Cl(4)](2) (17), [Rh(CO)Cl(10)](2) (19), and [Rh(CO)Cl(13)](2) (20) were confirmed by X-ray crystallography. Ligands 4, 7, 10, 13, 16, and SPANphos were tested in rhodium catalyzed methanol carbonylation at 150 degrees C and 22 bar of CO gas, showing high activities under catalytic conditions.
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