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Jiang-Shan Shen1, Qing-Guo Cai, Yun-Bao Jiang

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Chemical Communications (Cambridge, England)
|August 24, 2010
PubMed

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...