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Room temperature ppb level Cl2 sensing using sulphonated copper phthalocyanine films.

Arvind Kumar1, A Singh, A K Debnath

  • 1Thin Films and Devices Section, Technical Physics Division, Bhabha Atomic Research Center, Mumbai 400 085, India.

Talanta
|August 31, 2010
PubMed
Summary

Sulphonated copper phthalocyanine (CuTsPc) films exhibit selective room temperature gas sensing for chlorine (Cl2). Irreversible responses at higher concentrations are due to chemical bond formation and oxidation of the CuTsPc film.

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Area of Science:

  • Materials Science
  • Chemical Sensing
  • Nanotechnology

Background:

  • Chemiresistive gas sensors are crucial for environmental monitoring and industrial safety.
  • Copper phthalocyanine (CuPc) derivatives are promising materials for gas sensing applications.
  • Sulphonated CuPc (CuTsPc) offers potential for enhanced selectivity and sensitivity.

Purpose of the Study:

  • To investigate the room temperature chemiresistive gas sensing properties of drop-casted CuTsPc films.
  • To determine the selectivity and sensitivity of CuTsPc films towards chlorine gas (Cl2).
  • To elucidate the mechanism behind the sensor's response and potential limitations.

Main Methods:

  • Drop casting of sulphonated copper phthalocyanine (CuTsPc) to form thin films.
  • Chemiresistive gas sensing measurements at room temperature.
  • X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) analysis.

Main Results:

  • CuTsPc films demonstrated high selectivity for Cl2 gas at room temperature.
  • Linear sensitivity ranging from 65% to 625% was observed for Cl2 concentrations between 5 and 2000 ppb.
  • Irreversible sensor response at concentrations >= 2000 ppb was attributed to chemical bond formation.
  • XPS and FTIR data confirmed the oxidation of the SO3Na group by Cl2 gas.

Conclusions:

  • CuTsPc films are effective room temperature chemiresistive sensors for Cl2.
  • The sensor's performance is limited at high Cl2 concentrations due to irreversible chemical reactions.
  • Understanding the degradation mechanism is key for developing robust Cl2 gas sensors.