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Direct ethanol fuel cell using hydrotalcite clay as a hydroxide ion conductive electrolyte
Kiyoharu Tadanaga1, Yoshihiro Furukawa, Akitoshi Hayashi
1Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan. tadanaga@chem.osakafu-u.ac.jp
Abstract:
An alkaline-type direct ethanol fuel cell (DEFC) using a natural clay electrolyte with non-platinum catalysts is proposed. So-called hydrotalcite clay, Mg–Al layered double hydroxide intercalated with CO₃²⁻, is shown to be a hydroxide ion conductor. An alkaline-type DEFC using this natural clay as the electrolyte and aqueous solution of ethanol and potassium hydroxide as a source of fuel exhibits excellent electrochemical performance from room temperature to 80 °C.
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