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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Amphiphilic photo-isomerisable phosphanes for aqueous organometallic catalysis
Hervé Bricout1, Estelle Banaszak, Christophe Len
1Université de Lille Nord de France, CNRS UMR 8181, UArtois UCCS, Faculté des Sciences Jean Perrin, rue Jean Souvraz, SP 18, F-62307 Lens Cedex, France.
Abstract:
Water-soluble phosphanes were tagged with a light-responding diazo group. Upon UV exposure, the diazo-isomerisation led to phosphane morphology change, resulting in an increase in the reaction rate of an aqueous palladium-catalysed cleavage reaction.
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