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Synthesis of Hydrogels with Antifouling Properties As Membranes for Water Purification
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Reduction of surface hydrophobicity using a stimulus-responsive polysaccharide.

Iliana G Sedeva1, Daniel Fornasiero, John Ralston

  • 1Ian Wark Research Institute, University of South Australia, Mawson Lakes, Adelaide, SA 5095, Australia.

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Carboxymethyl cellulose (CMC) adsorption on hydrophobic surfaces is influenced by ionic strength and pH. Changes in these conditions alter CMC hydration and surface hydrophobicity reversibly, impacting its effectiveness.

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Area of Science:

  • Surface Science
  • Polymer Chemistry
  • Materials Science

Background:

  • Carboxymethyl cellulose (CMC) is a widely used biopolymer with applications in various industries.
  • Understanding CMC adsorption behavior on different surfaces is crucial for optimizing its performance.
  • Hydrophobic surfaces present unique challenges and opportunities for polymer adsorption studies.

Purpose of the Study:

  • To characterize the adsorption of CMC onto a hydrophobic self-assembled monolayer.
  • To investigate the influence of solution conditions (ionic strength and pH) on CMC adsorption.
  • To examine the response of adsorbed CMC layers to changes in solution conditions and their effect on surface properties.

Main Methods:

  • Quartz Crystal Microbalance with Dissipation Monitoring (QCM-D) was used to quantify CMC adsorption and hydration.
  • Captive bubble contact angle measurements assessed the surface hydrophobicity.
  • Adsorption and surface property changes were studied under varying ionic strength (10(-2) M to 10(-1) M KCl) and pH (9 to 3).

Main Results:

  • CMC adsorption increased with higher ionic strength and lower pH.
  • Switches in solution conditions induced reversible release of hydration water from the adsorbed CMC layer.
  • Lowering pH caused more significant changes in hydration and conformation than increasing ionic strength.
  • Adsorbed CMC reduced surface hydrophobicity, with enhanced effects at low pH and high ionic strength.
  • Switches in solution conditions further enhanced CMC's ability to reduce surface hydrophobicity, reversibly.

Conclusions:

  • Solution conditions significantly control CMC adsorption, hydration, and conformational changes on hydrophobic surfaces.
  • CMC's ability to modify surface hydrophobicity is tunable by adjusting ionic strength and pH.
  • The observed hydration and hydrophobicity changes are reversible, suggesting potential for responsive material applications.