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Updated: Jun 8, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Chain mechanism for exchange of D2 with a ruthenium hydride
Charles P Casey1, Jeffrey B Johnson, Xiandong Jiao
1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI, USA. casey@chem.wisc.edu
Abstract:
The ruthenium hydride of (Ar(4)CpOH)Ru(CO)(2)H exchanges cleanly and rapidly with D(2) at room temperature to generate the ruthenium deuteride. A chain mechanism is proposed to explain the much more rapid exchange of RuH/D(2) than RuCO exchange with (13)CO.
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