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Related Concept Videos

Specific Heat01:16

Specific Heat

The specific heat capacity of a substance refers to the energy required to increase the temperature of one gram of that substance by one degree Celcius. Specific heat capacity is often represented in calories (cal), grams (g), and degrees Celsius (oC), but can also be expressed in joules (J), kilograms (kg), and Kelvin (K), among other units.
For example, increasing the temperature of one gram of water by 1°C requires one calorie of heat energy and can be written as 1 cal/g-°C, or 4186 J/kg/K.
Heat Flow and Specific Heat01:12

Heat Flow and Specific Heat

Heat is a type of energy transfer that is caused by a temperature difference, and it can change the temperature of an object. Since heat is a form of energy, its SI unit is the joule (J). Another common unit of energy often used for heat is the calorie (cal), which is defined as the energy needed to change the temperature of 1 g of water by 1 °C, specifically between 14.5 °C and 15.5 °C, since the energy needed shows a slight temperature dependence. Another commonly used unit is the kilocalorie...
Quantifying Heat02:46

Quantifying Heat

Thermal Energy Microscopically, thermal energy is the kinetic energy associated with the random motion of atoms and molecules. Temperature is a quantitative measure of “hot” or “cold”, which depends on the amount of thermal energy. When the atoms and molecules in an object are moving or vibrating quickly, they have a higher average kinetic energy (KE) (or higher thermal energy), and the object is perceived as “hot”, or it is described as being at a higher temperature. When the atoms and...
Absorption of Radiation01:05

Absorption of Radiation

The rate of heat transfer by emitted radiation is described by the Stefan-Boltzmann law of radiation:
Gauss's Law: Spherical Symmetry01:26

Gauss's Law: Spherical Symmetry

A charge distribution has spherical symmetry if the density of charge depends only on the distance from a point in space and not on the direction. In other words, if the system is rotated, it doesn't look different. For instance, if a sphere of radius R is uniformly charged with charge density ρ0, then the distribution has spherical symmetry. On the other hand, if a sphere of radius R is charged so that the top half of the sphere has a uniform charge density ρ1 and the bottom half has a uniform...
Joule-Thomson Effect01:21

Joule-Thomson Effect

The Joule-Thomson effect, also known as the Joule-Kelvin effect, describes the temperature change of a fluid when it is forced through a valve or porous plug while keeping it in a thermally insulated environment. This experiment is called a throttling process. This is an important effect widely used in refrigeration and the liquefaction of gases.
This experiment forces high-pressure gas through a throttle valve or a porous plug to a lower-pressure region. The gas expands as it passes through to...

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Characterization of Thermal Transport in One-dimensional Solid Materials
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Frequency-dependent specific heat from thermal effusion in spherical geometry.

Bo Jakobsen1, Niels Boye Olsen, Tage Christensen

  • 1DNRF Centre Glass and Time, IMFUFA, Department of Sciences, Roskilde University, Postbox 260, DK-4000 Roskilde, Denmark. boj@ruc.dk

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|September 28, 2010
PubMed
Summary

This study introduces a new method to measure frequency-dependent specific heat at the glass transition. The technique uses thermal waves from a spherical thermistor, allowing independent determination of thermal conductivity and specific heat.

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Area of Science:

  • Materials Science
  • Thermodynamics
  • Physical Chemistry

Background:

  • The glass transition is a critical phenomenon in amorphous materials, influencing their mechanical and thermal properties.
  • Accurate measurement of frequency-dependent specific heat is essential for understanding material behavior at the glass transition.
  • Existing methods for specific heat measurement often face challenges with boundary conditions and independent property determination.

Purpose of the Study:

  • To present a novel method for measuring frequency-dependent specific heat at the glass transition.
  • To apply this method to the material 5-polyphenyl-4-ether.
  • To independently determine thermal conductivity and specific heat using the developed technique.

Main Methods:

  • Utilizes thermal waves effusing radially from a spherical thermistor.
  • The thermistor functions as both a heat generator and a thermometer.
  • Employs the 3ω technique, accounting for higher-order terms.

Main Results:

  • Successfully measured frequency-dependent specific heat at the glass transition for 5-polyphenyl-4-ether.
  • Demonstrated the ability to independently determine thermal conductivity and specific heat.
  • Identified optimal frequency ranges for highest sensitivity based on thermal diffusion length.

Conclusions:

  • The presented method offers an advancement over planar effusion techniques due to analytically known boundary conditions.
  • The method measures longitudinal specific heat, providing distinct thermodynamic information.
  • This technique enhances the understanding of thermal properties of materials near their glass transition.