Related Experiment Video
Updated: Jun 8, 2026
Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
Published on: May 10, 2021
Distinct high-T transitions in underdoped Ba(1-x)KxFe2As2
R R Urbano1, E L Green, W G Moulton
1National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32306-4005, USA.
Abstract:
In contrast with the simultaneous structural and magnetic first order phase transition T0 previously reported, our detailed investigation on an underdoped Ba(0.84)K(0.16)Fe2As2 single crystal unambiguously revealed that the transitions are not concomitant. The tetragonal (τ: I4/mmm)-orthorhombic (ϑ: Fmmm) structural transition occurs at T(S)≃110 K, followed by an adjacent long-range antiferromagnetic (AFM) transition at T(N)≃102 K. Hysteresis and coexistence of the τ and ϑ phases over a finite temperature range observed by NMR experiments confirm the first order character of the τ-ϑ transition and provide evidence that both T(S) and T(N) are strongly correlated. Our data also show that superconductivity develops in the ϑ phase below T(c)=20 K and coexists with AFM. This new observation, T(S)≠T(N), firmly establishes another similarity between the hole-doped BaFe2As2 and the electron-doped iron-arsenide superconductors.
Related Concept Videos
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
02:42Valence Bond Theory
01:26Imperfections in Crystal Structure: Stoichiometric Point Defects
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
04:00Periodic Classification of the Elements