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Invariance of the correlation energy at high density and large dimension in two-electron systems
Pierre-François Loos1, Peter M W Gill
1Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, 0200, Australia. loos@rsc.anu.edu.au
Abstract:
We prove that, in the large-dimension limit, the high-density correlation energy Ec of two opposite-spin electrons confined in a D-dimensional space and interacting via a Coulomb potential is given by Ec∼-1/(8D2) for any radial confining potential V(r). This result explains the observed similarity of Ec in a variety of two-electron systems in three-dimensional space.
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