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Related Concept Videos

Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
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Hybridization of Atomic Orbitals II

sp3d and sp3d 2 Hybridization
Polymer Classification: Architecture01:14

Polymer Classification: Architecture

Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
Hybridization of Atomic Orbitals I03:24

Hybridization of Atomic Orbitals I

The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
Gravimetry: Inorganic And Organic Precipitating Agents00:49

Gravimetry: Inorganic And Organic Precipitating Agents

In gravimetry, the precipitant is chosen carefully to obtain a pure solid that can be easily filtered. Common inorganic precipitants can be used to determine several cations and anions. In some cases, the formation of the same precipitate can be used to determine the cation and the anion. For example, the reaction of barium and chromate ions to give barium chromate is used to determine both barium and chromate. However, precipitates such as hydroxides, oxalates, and metal ammonium phosphates...
Characteristics and Nomenclature of Homopolymers01:00

Characteristics and Nomenclature of Homopolymers

Polymers that are made up of identical monomer units are called homopolymers. Only one repeating unit is involved in the construction of the homopolymer structure. For example, as depicted in Figure 1, polypropylene is a homopolymer constituted of propylene monomers. Here, the only repeating unit in the polymer chain is propylene.

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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

Cluster-based inorganic-organic hybrid materials.

Ulrich Schubert1

  • 1Institute of Materials Chemistry, Vienna University of Technology, Vienna, Austria. Ulrich.Schubert@tuwien.ac.at

Chemical Society Reviews
|September 30, 2010
PubMed
Summary

This review explores cluster-based hybrid materials, including hybrid polymers and metal-organic frameworks. It highlights how varying cluster units and organic linkers offers diverse material possibilities.

Area of Science:

  • Materials Science
  • Inorganic Chemistry
  • Polymer Chemistry

Background:

  • Cluster units serve as fundamental building blocks for inorganic-organic hybrid materials.
  • Two primary categories exist: hybrid polymers and crystalline metal-organic frameworks.
  • These materials integrate inorganic clusters with organic components.

Purpose of the Study:

  • To provide a tutorial review on cluster-based inorganic-organic hybrid materials.
  • To illustrate the diversity and tunability of these materials.
  • To emphasize the spectrum between hybrid polymers and metal-organic frameworks.

Main Methods:

  • Co-polymerization of organic monomers with functionalized clusters for hybrid polymers.
  • Coordination chemistry using multifunctional organic ligands and cluster units for metal-organic frameworks.

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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
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  • Analysis of structural and property variations based on component modification.

    • Main Results:

    • Hybrid polymers are formed by cluster units crosslinking polymer chains via co-polymerization.
    • Metal-organic frameworks are constructed through coordination chemistry linking clusters and organic ligands.
    • Both material types represent limiting cases with extensive possibilities for structural variation.

    Conclusions:

    • Cluster-based hybrid materials offer a wide design space by modifying both cluster and organic components.
    • The distinction between hybrid polymers and metal-organic frameworks is not absolute but exists on a continuum.
    • This flexibility allows for the development of novel materials with tailored properties.