Multidimensional molecular steric opacity function for XeCl*(B, C) formation in the oriented Xe* (³P₂, MJ = 2) +...

The steric effect for the XeCl*(B, C) formations in the oriented Xe* (³P₂, MJ = 2) + oriented CCl₃F reaction has been observed as a function of the mutual configuration between the molecular orientation and the atomic orbital alignment in the collision frame. Molecular steric opacity functions have been determined as a function of the atomic orbital alignment (M(L)') in the collision frame. The XeCl*(B, C) channels show similar molecular steric opacity functions at M(L)' = 0 but not at |M(L)'| = 1. The large molecular alignment dependence (i.e., the reactivity of the Cl₃ end and the F end is comparable, but a very poor reactivity for the sideway) is recognized for the XeCl*(B, C) channels except for the XeCl*(C) channel at |M(L)'| = 1, which shows an almost isotropic molecular orientation dependence. The M(L)' selectivity is different between the XeCl*(B, C) channels. At the molecular axis direction, the XeCl*(B) channel has little M(L)' selectivity whereas the XeCl*(C) channel is significantly favorable at M(L)' = 0. On the other hand, |M(L)'| = 1 is favorable at the sideway for the XeCl*(B, C) channels.