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Updated: Jun 8, 2026

Proton Transfer and Protein Conformation Dynamics in Photosensitive Proteins by Time-resolved Step-scan Fourier-transform Infrared Spectroscopy
Published on: June 27, 2014
Practical example of the correction of Fourier-transform spectra for detector nonlinearity
Abstract:
HgCdTe photoconductive detectors can display a nonlinear response when illuminated. In interferometric applications, this behavior must be accounted for in the data transformation process to avoid errors in the measurement of the spectral distribution of the incident radiation. A model for the distortion of the interferogram is proposed and applied to solar observations made by the Atmospheric Trace Molecule Spectroscopy (ATMOS) Fourier-transform spectrometer during orbital sunrise and sunset from the Space Shuttle. Empirical estimation of the dc current level is necessary for this instrument, and satisfactory nonlinearity correction is obtained for several of the primary ATMOS optical filters. For ATMOS broadband optical filters that cover more than one half the alias bandwidth, the model is inadequate because of the presence of antialiasing electronic filters within the instrument, and it is necessary to resort to estimation and subtraction of the residual baseline offset. In either case the remaining base line offsets are typically smaller than 1%, which is satisfactory, although offset remains a significant systematic source of error in the estimation of the abundance of telluric and solar constituents from the spectra.
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