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The diammoniate of diborane: crystal structure and hydrogen release
Mark Bowden1, David J Heldebrant, Abhi Karkamkar
1Pacific Northwest National Laboratory, Richland, WA 99352, USA. mark.bowden@pnl.gov
Abstract:
[(NH(3))(2)BH(2)](+)[BH(4)](-) is formed from the room temperature decomposition of NH(4)(+)BH(4)(-), via a NH(3)BH(3) intermediate. Its crystal structure has been determined and contains disordered BH(4)(-) ions in 2 distinct sites. Hydrogen release is similar to that from NH(3)BH(3) but with faster kinetics.
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